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I have a few copper cartridges and am pretty sure that all copper cased cartridges were BP.
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Gary, I would assume that when you shoot these old cartridges that you would be able to tell the difference between a BP round and a smokeless round??? My only experience with BP is in my flintlock rifle and when I shoot it on our range there is no mistaking by anyone nearby that it is BP.
Being such a small case, does it also make quite a bit of smoke compared to its smokeless counterpart?