Largest and most powerful shoulder fired guns I've shot were the 20mm Lahti AT rifle and 20mm Gustav recoilless rifle.
Biggest bang that I've actually pulled the trigger on was a 57mm anti-tank gun out at the Big Sandy Machine gun shoot in AZ.
Some of the boys and their toys:
http://www.break.com/userconte...mage-llc-216765.html
My favorite part starts around 1:15... 90mm AT gun.