Jim Scouten on Shooting Gallery recently featured a tour to CCI to analyze various types of .22LR ammo.
As I recall, they rated Velocitors best for penetration, but they also showed a 'Segmented Hollowpoint' that was designed to fragment shortly after impact and, according to the ballistic gelatin tests, would indicate likely extensive damage to small game.
If cold weather and lots of layers of clothing aren't a factor, then the segmented hollowpoint round may be an option to evaluate.
Personally, I use CCI Mini-Mag Hollow points (36 grain) in the Walther P22 that my wife often carries.
The P22 is also fitted with a laser to aid with shot placement. I'd strongly recommend CT grips for your gun, if you can swing the cost.
As Erich pointed out shot placement is key in any shooting situation, but essential with a .22LR
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