I have not used Prvi .38 Special brass, but I have used Prvi .38 S&W brass. It is also definitely thicker than R-P and W-W brass in this caliber. It works fine in my S&W Victory and a Colt Police Positive. I wouldn't hesitate to use Prvi .38 Special brass. Revolver brass usually fails with case neck splits, which means it's time to toss it.
As far as using foreign components, I've used bullets, brass, powder, and primers from Brazil, Italy, Czech Republic, Israel, Finland, Sweden, Mexico, Russia, and Bosnia-Herzegovenia. I've never had problems with any of them or with American components.
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