Since leather is flexible and holsters are made with less precision than a firearm or most things made of metal, you can't say that it won't fit with absolute certainty, but I think it would be very unlikely.
Frontier .44's are big guns, so they take a big holster. The fact that they are not proportioned like modern firearms adds to the non-fitting issue.
Note that both of us who have responded here have had custom holsters made up for our Frontiers.
The closest of the production holsters that I found in terms of fitting was for the original model Ruger Vaquero. They are bigger than Colt SAA's so their holsters run large, also. It's not a great fit, but it's better than nothing.
However, since holsters vary, as I said above, your best bet is to take the S&W to a gun show and try to see what fits, until you either find one, or not.
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