Yep, the flash-chromed hammers and triggers started going away in the mid-to-late 90's as the MIM parts were being produced.
The older machined hammers were also made available in black for some models.
I don't pretend to have anything like a definitive answer, but here's some hammers I grabbed out of my parts bins.
The 2 hammers on the left (spurless) are both machined carbon steel hammers. The flash-chromed hammer is for an early production 3rd gen 6906. Notice it has some serrations at the top. The black finish spurless hammer next to it is newer and listed as a part for one of the later production Value Line guns. It lacks the serrations on top.
The 2 hammers on the right are both MIM. You can see the indentations in the sides which indicate it's a MIM part.
Now, the triggers can be a little interesting. I've seen a bit of variance in the machining & finish of the older machined triggers, in the area of the "prongs" (or hooks) which ride in the V-notch of the drawbar head. The MIM triggers have always seemed to be much smoother and more uniformly shaped in that area.
The older machined hammers could have anywhere from a very smooth to a very rough surface on the rounded front surface, depending on the sharpness of the cutter used when it was made. The MIM hammers are uniformly smooth. (Something you might notice in a DA trigger stroke.)
The 9/.40 triggers were also a bit wider in the models which had wide frames (for double column mags), compared to say, a 3913. The MIM triggers were narrower across the face than the older machined triggers in the wide frames guns, and had a slightly rounded, higher center instead of being as flat across the face as the older machined triggers. I had mixed feelings about the slightly narrower and rounded face MIM triggers ... until I'd invested a lot of range time with them in a 59XX gun. Then I decided I liked them. Quite a bit.
I can't remember comparing the older .45 triggers (4516 v. 645/4506), though.
While I've heard conflicting info from factory sources (including in different armorer classes) about mixing machined & MIM hammers and sears in TDA guns, for the sake of optimal long term functioning, when it comes to matching hammers & sears I'd keep MIM with MIM and machined with machined. (In DAO guns it's absolutely required to keep machined/machined & MIM/MIM when it comes to matching hammers and sears. There are distinct angle differences between the old and new DAO parts.)