The #11 Speer Reloading Manual lists a variety of powders for their .451" 260-grain hollow point:
6.6-7.2 grains of 800X
6.3-6.9 grains of Herco
5.8-6.4 grains of SR4756
5.8-6.4 grains of Unique
5.4-5.9 grains of 231
5.3-5.8 grains of Green Dot
5.1-5.6 grains of SR7625
4.7-5.2 grains of Bullseye
4.6-5.1 grains of Red Dot
4.6-5.0 grains of 452AA (long discontinued, I believe...)
4.4-4.9 grains of 700X
Additionally, the second Accurate Arms manual shows these loads for a "250 (L) SWC:
3.8-4.2 grains of S100
4.7-5.2 grains of AA #2
6.4-7.1 grains of AA #5
8.6-9.5 grains of AA #7
10.8-12.0 grains of AA #9
Finally; somewhere, I have a listing in an old Speer manual for loading the Lyman 454424 in the ACP, but for the life of me cannot find it. But I am trying to say that this has been done a lot before, and especially in your 625, there should be no problem. I would use the 260-grain load information, extrapolate and load up slowly, or use the AA load data as printed, assuming you have their powders on hand.
One additional note: if you have Unique, I would recommend trying the loading data for AA #5, reducing charge weights by a full grain and working up.
Good luck!