Thanks all for the responses. I'll try to incorporate some of the suggestions so far.
Are you in CA? Are you feeding the round in from the magazine?
It is the CA model with LCI. Rounds are being fed only from mag.
How old is the gun? How many rounds?
Was it only once or has this happened many times?
A picture would help.
Sorry, didn't get pics. It's a relatively new gun, but I've already got close to 1000 rounds through it.
This happened only twice. 1 time with a Federal FMJ round. I tried to load that specific round again from a different mag and by manually slingshotting the slide and that round would not chamber properly at all.
2nd time, happened yesterday. I was trying some new ammo in it. Blazer FMJ Aluminum that was $8 a box online. I tried loading that round in a different mag and it chambered and fired properly.
That was my first thought also. It needs to be fired several hundred more times and also with some hot ammo.
Looks like the OP recently bought the Shield, from his first post on 19 July.
That's some nice detective work! Yes, it's a new gun, but I do have close to 1000 rounds through it. As to hottness, they've been mostly Federal FMJ, MagTech, Federal HST, WWB JHP 147gr, and Train and Defend JHP 147gr. Yesterday, I tried some Aguila FMJ and Blazer FMJ.
As the OP stated that the LCI wasn't activating (I don't have one with the LCI but I think I know how they work), sounds like the cartridge base isn't flush up against the breech face, so maybe the extractor isn't slipping over the rim and is keeping the slide out of battery. I don't know how experienced the OP is, he might not notice whether the slide is fully forward or not.
As it's presumably a new gun, I could see how some machining crud could get into the extractor slot at the factory and cause the extractor not pivot the way it's supposed to.
He can check this by hand cycling some of the offending cartridges at home.
Not super experienced, but I'm learning. I had heard of the slide not going forward on Shields and so I did try to pay attention and I'm pretty sure it was all the way forward.
New gun, but I shoot a few times a week approx 150 rounds each time, and I clean and lube meticulously after every range trip. I get a toothpick with some solvent to clean out crud under the extractor. Also, gun was cleaned and lubed prior to shooting it the first time.