It takes a good eye, but you should be able to compare the sight base to the blade. If it looks good, it may be that the barrel is canted. Maybe when the gun was reblued, the barrel was removed. When replaced and it could have been not tightened enough. It would have taken a new hole being drilled in order to put the barrel retaining pin in place, but could happen.
It the blade looks skewed as compared to the sight base, it needs to be bent back into place. I have used hardwood (maple or oak) in the past that worked fine if you do not have lead around. Take wwo 3/4" pieces and clamp them together, then drill a hole the size of the barrel down between the two pieces of wood. Take both of them and carve out the sight base area, then lay the barrel in and clamp the the wood and gun barrel to the work bench or place in a vise. I use either a small plastic hammer or a large brass punch to move the blade. Check often until back in position.