If you take a close look at the pictures the op posted you can see finger prints in the "soot". That's consistent with bullet lube, hence my statement about the nra 50/50 lube.
The picture I posted of the 200 round count revolver with the "carbon" buildup is completely different.
The op's brass is sealing or you would see the soot marks on 1 side of the case by the case mouth.
With a 38spl/revolver reload the only thing holding the bullet in place is neck tension and crimp. When you hit the loud button (trigger) the hammer hits the primer and "BANG", the bullets off to the races. Well, not so fast. The primer itself can and will push the bullet out of the case and forward. The primer ignites the powder and as the burning powder builds pressure it is also pushing the bullet forward.
This is where that short start pressure thing comes into play.
When that bullet starts to move forward out of the case the case itself is also moving towards the rear of the revolver. Until the case hits the shield (reseating the primer) and the bullet enters the leade of chamber. There is a small window of opportunity for gas blowby. With a lead/lubed bullet part of the blowby contains partially burnt bullet lube.
When the case is against the shield and can't move anymore & the bullet is entering the narrow leade of the chamber. The pressure of the load will start to build ending the short start pressure cycle.
At this phase the building pressure is applying pressure to the bullets base. This pressure collapses/compresses the lube groove forcing the lube outward. Some of the hot gas gets by the base and pushes the lube forward as it keeps burning it. The bullet enters the forcing cone and encounters it's first real mechanical resistance. This resistance allows the pressure of the load to compress the bullets base until it bumps up to the diameter of the leade of the chamber sealing the chamber. As the bullet moves forward the bullets base jumps the forcing cone/cylinder gap and more soot is thrown everywhere. Once the bullets base is past the forcing cone and in the bbl. The pressure of the load is still compressing the bullets base forcing the lube outward and forward with hydraulic pressure. Some of the hot gasses/pressure gets past the bullets base/bottom drive band and pushes the lube forward lubing/sealing the forward drive bands.
Myself, I always viewed bullet lube as a gasket more then an actual lube.
I've showed this picture before, it recovered cast bullets. I received this from a member on another website years ago. We were discussing the difference between round vs square lube grooves.
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If you look closely you at the lube grooves of the recovered bullets you can see that they are compressed/smaller than the unfired bullets above them. This is that compression and the lube thing I was talking about.
My uncoated lead SWC are lubed. I ran out of copper XTreme bullets but have some now on hand and will see if I load up more to see if the sooting is the same. I only had a couple for snubbie shooting since I loaded them mostly for 357Mag and shooting them from my Marlin lever.
Maybe going to the max of the COL might help with the lead SWC.