The most notable of smokeless powder deterioration incidents were batches of WWII IMr 4831 (USED IN .50 bmg and 20mm cannon) and Korean War era production of ball powders. Nitric acid is one of the components of smokeless powder manufacture, and it is normally completely removed during processing. However, during the rush of wartime production, acid residues left in the nitrocelluose accelerates powder deterioration, hence the reddish dust or evident of rust inside a metal powder container. A distinct sour or acrid smell is also characteristic. Not the sweet aromatic of alcohol and ether fumes, but sour smell. Since small arms propellents were made in such humongous quantities (railroad boxcar "lots"), much of it was available as surplus to post WWII hobbiest reloaders, and that is where we hear about surplus powder deterioration.
Ammo made in the 1930s can be remarkably stable, because this was before the wartime manufacturing frenzy.