Rule 3,
Now, the practical end of all this. If you are wanting to measure a S&W barrel, you can't do it without the proper guage block, so save your time. Instead of trying to measure the slug, see if it will pass freely through the throats of the cylinder, you don't have to know how big it is. If it passes through the throats then they are big enough.
More important for accuracy is bullet fit to the throats, not the bore, that is what the forcing cone does. If the slugs pass through the throats with little or no resistance then slug the throats. The round slug from the throat you cam measure! Once you know the throat diameter you order your bullets from a company which will size to the requested dimension. If you are casting yourself, size your bullets to either the diameter of the throats (or largest one) or .001 larger.
The only real reason to slug your bore is to be sure the throats are at lease that large so the throat doesn't size your bullet under groove diameter. If you want good accuracy, and the slug takes too much pressure to pass through the throats you need to open the throats until the bore slug does pass with only a few ounces pressure. Then go back and slug the throats, etc.
Notice, that while it may be of interest to know the groove diameter of your barrel it is absolutely unnecessary to know this dimension, only that the cylinder throats are as large or larger.