Vinny - So the sequence of events was:
1. Normal trigger pull,
2. Possibly stronger than normal impulse,
3. The bolt cycles open but does not eject the entire case, and
4. As the bolt cycles a small piece of the casing is ejected and hits your leg.
If this is correct then I'm thinking either barrel obstruction or overly hot load - either would over-pressurize the chamber and may damage the case causing a blow-out. My only other thought would be a very thin (way out of spec) or damaged/split case that couldn't hold standard pressure and burst.