Kevin,
What several others have recommended. 4.0 gr. Unique, is a very good load. There is one exception I need to tell you about and that is primers for the .32-20 in revolvers, and this is very important! I have been loading this cartridge for over 65 years for the second S&W, and several others, that I own. This is a Model 1902 1st change.
Most manuals recommend using the small rifle primer, and there is a very good reason for this, although I have never seen an explanation for it in any manual. This is why. The .32-20 in a revolver has a bad tendency to squib, which can result in a bulged barrel if another round is fired if the squib is not noticed. I have seen many, dozens, of .32-20 revolvers with bulged barrels, including my own Model 1902! (It was that way when I bought it.) All I have seen have been S&Ws for an unknown reason! I have two friends who have had squibs and, unfortunately, have bulged the barrels of previously perfect revolvers!
Using the small rifle primer in revolvers greatly, if not totally, eliminates experiencing squibs with this cartridge. I very strongly recommend heeding this warning. There is absolutely no reason to use small pistol primers, the cost is the same. I have always used small rifle and have never had a squib or mis-fire in all 65 years!