When the Mk I Webley Service Revolver was introduced to service the calibre was given as .441" (sometimes quoted as .442"); ie bore and not groove. The introductions to service of all the subsequent marks (II-VI) never mentioned calibre; only the differences from the previous Mark. Later drawings show the groove depth as nominally .005", giving a groove diameter of .451" or .452" as you prefer. The chamber mouths were nominally .450".
The introduction to service of the Mk I "Cartridge, S.A., Ball, Pistol, Webley" had a drawing of the round with the lead bullet diameter given as .455". The whole idea was to ensure that the black powder charge had time to build up pressure before the bullet reached the barrel throat. None of these dimensions were changed in subsequent guns or cartridges.
.455" was only ever mentioned in official nomenclature when the Mk VI jacketed bullet was introduced in 1939 ""Cartridge, S.A., Ball, Revolver, .455inch, Mk VI". Note that originally (from 1854) revolvers were known as "Pistol, Revolver" since they replaced earlier single shot pistols.
Peter