I want to parrot back things I think I know (and their relationships) to be sure I get what you're saying:
* There is no question there is a linear relationship between seating depth and internal volume of the case. This situation is completely independent of the particular powder being used. The internal case volume is the internal case volume - whether it has a little or a lot of powder in it. I agree with Pi*R^2*H for calculating volume. (I know the internal of a case isn't a perfect cylinder. But I would argue that there is a linear relationship between seating depth and resulting internal volume that the powder can occupy in and burn in.)
* What pressure is generated as a result of that volume is not only the most important consideration, but also the most difficult to predict. The pressure that is generated is a function of the actual powder used (Does it burn fast or slow? Is it compressed or not?), the bullet weight used, and also a variety of other things that are even tougher to deal with such as actual bullet diameter relative to that particular gun's barrel diameter, whether the bullet is touching the lands or not, etc. All of these variables come together to produce some amount of pressure that, we all hope, is below max.
So this is why I go back to summarizing it as:
* The relationship between bullet seating depth and internal case volume (space powder occupies) is linear.
* The relationship between internal volume powder can occupy and resulting chamber pressure is non-linear.
Am I representing the physics correctly?