Nickel is probably like chrome,, it can not be directly plated to steel.
There can be one to three other layers of plating that goes on before the top layer of plating.
With chrome, the copper is plated on, then the easily buffed copper layer is perfected.
If you put chrome directly on the steel, it would pop off easily,,
the inner layers of plating allow a better bond.
So, whether the nickel is an alloy, or not, there are still other metals present.