AS has been mentioned, the 9x21 is a political cartridge. It is the 9x19 case lengthened to prevent chambering in a 9x19.
The 9x21 did find some use in practical pistol competition loaded (very) hot to make the Major power factor. Now that the rules allow loading the 9x19 to those high pressures to make Major, the 9x21 in the US is more of a curiosity.
That S&W made guns in 9x21 for the Italian (and apparently Swiss) markets, it resulted in the 356 TSW becoming a 9x21.5. Originally the 356 TSW was going to be a hot loaded 8x21.
I have not tried it, but, in all likelihood, you may be able to use 9x19 ammo in the 9x21 chamber, but if you reload, I believe Starline has 9x21 cases. There may also be some factory 9x21 ammunition available, but you may need to do some looking to find it. Stay away from any reloaded 9x21 that you do not know the history of the load in case it's some of the competition hot loads.