Just when does this occur and looking at the primers while fired brass is still in cylinder, to which side of center are the firing pin marks?
If the marks are all to the right of center as your looking at them, this maybe the cause.
N frame 357s have the heaviest cylinder of any double action revolvers. If used for fast DA shooting or rapid dry firing the rapid turning of that mass and its slamming to a stop as stop is slammed into the back of the stop notch can cause a metal displacement and a couple issues. The back side of the cylinder's stop notches, the part with no lead in groove, gets battered. Look at yours and feel for raise metal displaced by the stop slamming into it. It don't take a whole lot to change good lock up. If there is some take a small smooth faced hammer and tap tap tap on the raised part to move it back down into the notch. Material was not worn away just displaced. Now do the same thing at the little window in the frame where the stop comes up out of it. Power custom sells an over sized stop. But, careful peening and maybe a new factory stop and spring should restore proper function