This is from the manual I developed regarding bluing of the M9 pistol at the USAF gunsmith shop. These were for USAF General Officers.
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3. Bluing
Bluing (i.e., hot bluing) is a chemical process for achieving an attractive finish on steel gun parts. It is essentially a controlled rusting process in which a very thin layer of black iron oxide (Magnetite, Fe3O4) is chemically formed on a steel surface. While bluing alone provides a small degree of protection against abrasion and corrosion, its principal function is cosmetic. Hot bluing cannot be used on non-ferrous metals such as aluminum or brass, or on stainless steel. In fact, the chemical bluing bath will attack and destroy aluminum. If it is necessary to impart a blue-black finish to such metals, other methods must be used.
Even though a blued finish can be applied to any clean steel surface, its final appearance will be no better than the surface finish of the bare metal. If a bead-blasted steel surface is cleaned and blued, the blued surface will have the same dull frosted or satin appearance as that of the bare metal. If done well, this finish is not necessarily unattractive, and some gun manufacturers produce such finishes on their guns because bead blasting is much faster and less costly than hand polishing. However, the highest-grade gun finish is a bright deep blue, which requires a mirror-like surface finish on the base metal.
a. Parts cleaning- It is impossible to obtain a uniform blue finish unless the steel parts to be blued are free from corrosion, dirt, and grease. Therefore, cleaning polished parts thoroughly prior to bluing is essential to the success of the entire finishing process. In the gunsmith shop, considerable time often elapses between the completion of the surface preparation of the parts and the bluing process. The polished parts are therefore submerged in containers of cleaning solvent to prevent surface corrosion prior to bluing. It has also been discovered that the parts cleaning solvent itself does not do a complete job of removing grease and wax from the metal surface deposited by the polishing operation. Immediately prior to bluing, the parts to be blued are removed from the cleaning solvent bath, thoroughly wiped with paper towels, blown off with an air gun, then wiped carefully using paper towels and methyl ethyl ketone (MEK). The procedure used is to spray parts with MEK using a plastic spray bottle, followed by wiping them with a paper towel. Care must be used when MEK is used, because it is very flammable and contact with skin can cause dermatitis (removal of body fats from the skin) in some individuals. MEK must always be used outdoors or in a well-ventilated area, no smoking or open flames can be allowed close to the workspace, and operators should use proper personal protective equipment, especially polyethylene or rubber gloves. Use of gloves also prevents contamination of gun parts by body oils through skin contact during handling.
b. Bluing- The bluing process requires proper safety procedures to be followed. Solutions used are very hot, and the bluing chemical is caustic and can cause blindness if allowed to contact the eye. Therefore, the use of rubber aprons, boots, gloves, and eye protection is mandatory.
The bluing process begins by thoroughly cleaning the parts to be blued, as previously described. The earlier procedure was to immerse them in a boiling detergent (similar to that used in automatic dishwashers) bath while suspended from rods on fine steel wire, followed by rinsing in a hot water bath, and then into the hot bluing chemical bath. More recently, since MEK wiping has begun (as previously discussed), it has been determined that immersion in a hot detergent bath is unnecessary prior to hot bluing. After cleaning, smaller parts are placed in baskets rather than being individually suspended. Some parts may be placed together on rods (such as hammers and triggers), while slides are mounted on a special fixture, or rack.
A commercial hot bluing chemical is used, Oxynate 7, from Brownell’s, Montezuma IA. The chemical is dissolved in water for use, according to product instructions. For use, it is very important to maintain the bluing chemical bath at the proper and constant boiling temperature (290 – 295 degrees F.). This is done by adding water as necessary to replace water boiled off. If the temperature of the bath will not reach the desired boiling temperature range when the proper liquid level in the tank is maintained, then additional Oxynate 7 should be added. The parts, which are either racked or in baskets, are then immersed in the bluing chemical bath, visually inspected periodically during the bluing process, and removed when bluing appears to be complete. The residence time of parts in the hot bluing tank will typically be about 30 minutes.
c. Post-bluing – When bluing is determined to be satisfactory, the parts are removed from the bluing tank and immersed in a cool water rinse bath directly below the bluing tank. They are then inspected once more (preferably in daylight) to determine that no further immersion in the bluing tank is necessary. If the blued finish is satisfactory, the parts are then immersed in a hot water bath (to dissolve any residual bluing salts) followed by immersion in a hot water displacing oil bath (also a Brownell’s product) which prevents further corrosion by any remaining bluing chemicals. Upon removal of the parts from the oil bath, followed by draining, the bluing process is essentially complete.