Some good advice, Jessie. Here's my two cents worth...and it might not even be worth that.
Anyway...we used to have skunks all over the place. They'd taken up residence under my neighbor's shed, also under his porch and his chicken coop. Another one was also under my other neighbor's house. I've found one in one of my dog kennels once. If you're seeing them during the day, they've probably got rabies. You can count on it.
Here's how I got rid of them. I used a live trap, as was explained in other posts. I normally bait mine with leftover chicken wing bones after having a lunch of buffalo wings. But, like others have explained, tuna, cat food, and a variety of other stuff works well, too.
After I caught the skunks, it was always a .22 to the head from about 25 yards out. I wouldn't get much closer because they can spray a pretty good distance. One of my neighbors walked up to a trapped skunk once and shot the thing in the head with a .22 pistol. The thing flipped over and started gyrating, spraying poor ol' Larry all over. Sure, it was dead all right, but it got its vicarious revenge nevertheless.
I never tried to relocate them because 1) they've been known to cut loose either when you try to put the blanket over the trap or when you try to release them and, 2) by relocating them, all you're doing is moving the problem someplace else.
Now, here's the tough part....after you shoot them, they almost always release. Sometimes they won't release for a couple of minutes after they've been killed, but they
will release. They might not necessarily
spray, but as they relax, they will automatically eliminate bodily fluids.
You have to remember, their brain is about the size of a jawbreaker. If the .22 is deflected a little by the wire mesh of the trap, you might be off a little. If that happens, and you still hit him, he'll start flopping around and spraying like gangbusters. Take it from one who knows...that ain't a pretty sight. (And don't forget poor ol' Larry's experience.)
Good luck. Personally, I hate the little creeps. They kill chickens, raise havoc, carry rabies, and are just a down-and-out pure nuisance.