I'm guessing you're right about it being the shoulder at the throat of the chamber. I think rounds like .45 acp would head space there.
Should be right about the end of the cartridge, and the bullet would 'rest' in the throat, just ahead of the forcing cone.
I *think* the leade is the inside of the forcing cone where the bullet is smushed (dang, I just love technical talk) down to bore diameter. That, or it's that final jump in space from the throat of the chamber to where the forcing cone starts doing it's dirty business.