Allegedly, the "S" was added to the SN, e.g., SV XXXXXX, for revolvers originally manufactured with the early 1945 hammer safety improvement. Revolvers which were converted post-manufacture could have an "S" stamping in various places. I don't know much about the history of post-manufacture safety conversions, but I do remember a posting here regarding several thousand being done at the S&W factory for a fairly expensive amount per gun after the war, about half the cost of a new gun. I suppose it's possible that some conversions may have been done at locations other than at S&W, possibly at military arsenals, but I don't remember ever reading about that happening. It's not a simple drop-in conversion, and requires some machining operations.