Copper solvents long term harm?
Had an off and on correspondence with Mr. Wil Schumann, barrelmaker extraordinaire back in the early 2000's regarding some research he and other barrel makers did concerning barrel cleaning, accuracy, erosion, wear and barrel life. It was published in either of two now defunct but wonderful publications, "Tactical Shooter" or "Precision Rifle" back in the mid 90's. Bottom line, any sort of solvent will continue to work on barrel steel unless completely, completely flushed out. Subsequent fouling will trap solvent that will continue over time to eat at whatever it can, thus, increasing the rate of wear in a tube.
Mr. Schumann's and his team's conclusion was that- particularly with regard to jacketed ammo- a good quality barrel will foul up to a point and stay there. Best bet is to focus on keeping the chamber of your firearm clean but largely leave the barrel alone.
Since then I've followed his advice on my pistols and rifles. Particularly my issue pieces, that have seen thousands of rounds of jacketed ammunition, I've found that they've maintained good, consistent accuracy, even better than most all of my colleagues who run brushes and solvents down their bores. Once in a while I'll scrub with Kroil or Mili-Tec and JB bore paste out of a probably misplaced sense of guilt but really I find that following Wil Schumann's advice I've saved a lot of time cleaning and think that my rifles, carbines and pistols have been better off for it.