"Headspace" or more properly casehead-to-recoil shield clearance in a revolver will be the same for a rimmed versus a rimless cartridge. It should be a nominal 0.006" to 0.008" between the casehead and recoil shield, measured using an automotive feeler gage.
You can measure this with cartridges or cases held in moonclips, but if you do not use moonclips, be aware that some models of M625 have been reported with chamber rims cut too deep to function properly without moonclips.