Internal ballistics are well studied and all the mathematics were well established in the relatively early in the 1900's.
Here is a list reading material/references that will help you better understand what is happening once the primer is ignited.
Once you start to understand the basics you should be able to see the limitations of concepts like duplex loads, primer extension tubes and the numerous other experiments that individuals concoct.
If any of these really were reasonable successful the would be common in the market place.
"Interior Ballistics of Guns" Engineering Design Handbook Gun Series, AMCP 706-150, 1965
This is a more serious effort and is on a par with Hunt's "Internal Ballistics" i. The experimental methods described date from the WWII. This is available online
F. R. W. Hunt "Internal Ballistics" The Philosophical Library, 1951
An edited collection of contributions by a number of British ballisticians. It goes into the basic theory of internal ballistics with a good description of the experimental work and methods. This is available online
J. Corner "The Theory of the Interior Ballistics of Guns" Wiley, 1950
The "classic" text on the theory of internal ballistics. A statement of the state of the art in British research at the end of WWII. This is available online.= a must for students of internal ballistics bookshelf
If you are interested in an expanded list PM me